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发布日期:2021年12月03日
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Rhenium-185 and rhenium-187 NMR

Home and Applets > Periodic Table > Rhenium
IsotopeSpinNatural
abundance (%)
Quadrupole moment
(10-30m2)
Relative
sensitivity
Absolute
sensitivity
NMR frequency (MHz)
at a field of 2.3488T
Reference
sample
Re-1855/237.07218.00.134.93E-2-22.513KReO4
Re-1875/262.93207.00.138.62E-2-22.744

Solid-state rhenium NMR references

  1. C. M. Widdifield, A. D. Bain, and D. L. Bryce
    Definitive solid-state 185/187Re NMR spectral evidence for and analysis of the origin of high-order quadrupole-induced effects for I = 5/2,
    Phys. Chem. Chem. Phys.13, 12413-12420 (2011).
    Abstract
  2. R. W. Schurko, S. Wi, and L. Frydman
    Dynamic effects on the powder line shapes of half-integer quadrupolar nuclei: a solid-state NMR study of XO4-groups,
    J. Phys. Chem. A106, 51-62 (2002).
  3. O. Vyaselev, K. Kobayashi, K. Arai, J. Yamazaki, K. Kodama, M. Takigawa, M. Hanawa, and Z. Hiroi
    Cd and Re NMR/NQR in pyrochlore compound Cd2Re2O7,
    J. Phys. Chem. Solids 63, 1031-1034 (2002).
  4. J. A. Davies and S. Dutremez
    Solid state NMR studies of d-block and p-block metal nuclei: applications to organometallic and coordination chemistry,
    Coord. Chem. Rev.114, 201-247 (1992).
  5. C. Dimitropoulos, M. Maglione, and F. Borsa
    Nuclear magnetic and quadrupole resonance in metallic powders in the presence of strong quadrupole interaction: Rhenium metal,
    Phys. Rev. B37, 3159-3163 (1988).

Related bibliography

  1. José C. Vites and Mary M. Lynam
    Rhenium 1993,
    Coord. Chem. Rev.146, A207-A224 (1995).
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